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Beilstein J. Org. Chem. 2018, 14, 2002–2011, doi:10.3762/bjoc.14.175
Graphical Abstract
Figure 1: Examples of chiral bimetallic complexes utilized in asymmetric catalysis.
Figure 2: Previously reported bisoxazoline ligands capable of stabilizing bimetallic complexes.
Scheme 1: Synthesis of naphthyridine–bisoxazoline ligand 16-H2.
Figure 3: Thermal ellipsoid plot (50% probability) of the molecular structure of 16·Ni2(OAc)2. Hydrogen and s...
Scheme 2: Synthesis of naphthyridine–bisoxazoline ligand 22-H2.
Scheme 3: Synthesis of pyrazole–bisoxazoline ligand 25-H3.
Figure 4: Thermal ellipsoid plot (50% probability) of the molecular structure of 25·Ni2(OAc). Hydrogen and so...
Scheme 4: Synthesis of pyrazole–bisoxazoline ligand 30-H3.
Figure 5: Thermal ellipsoid plot (50% probability) of the molecular structure of 30·Pd2Br. Hydrogen and solva...
Scheme 5: Synthesis of pyridazine–bisoxazoline ligand 32-H2.
Figure 6: Thermal ellipsoid plot (50% probability) of the molecular structure of 32·Zn2Cl2. Hydrogen and solv...
Scheme 6: Synthesis of phenol–bisoxazoline ligand 34-H3.